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Product Name: Titanium tetrachloride
CAS: 7550-45-0
Molecular Formula: Cl4Ti
Molecular Weight: 189.68
EINECS: 231-441-9
Appearance: White crystal powder
Dangerous goods transport Code: UN 3289 6.1/PG 2
Physical properties:
Titanium tetrachloride is a colorless liquid with high density, and the impure sample is often yellow or reddish brown. Similar to vanadium tetrachloride, it is one of the few transition metal chlorides that are liquid at room temperature, and its low boiling point is related to weak intermolecular forces. Most metal chlorides are polymers and contain metal atoms connected by chlorine bridges, while the intermolecular forces of titanium tetrachloride are mainly weak van der Waals forces, so the boiling point is not high.
The TiCl4 molecule has a tetrahedral structure, and each Ti4+ is connected to four ligands Cl鈭? Ti has the same number of electrons as the rare gas argon and has a closed shell structure. Therefore, the titanium tetrachloride molecule has a regular tetrahedral structure with a high degree of symmetry.
TiCl4 is soluble in non-polar toluene and chlorinated hydrocarbons. Studies have shown that the process of dissolving in some aromatic hydrocarbons involves the formation of similar [(C6R6)TiCl3]+ complexes. Titanium tetrachloride can react exothermically with Lewis base solvents (such as THF) to form a six-coordinate adduct. For larger ligands, the product is five-coordinated TiCl4L.
In addition to releasing corrosive hydrogen chloride, titanium oxide and oxychloride are also generated when storing TiCl4, which can stick to used stoppers and syringes.
ListSpec
Main Content: TiCl4%鈮?9.94
Color 锛孠2Cr2O7mg/L鈮?
Impurity Analysis(wt%)SiCl4 %鈮?.01
VOCl3 %鈮?.0024
FeCl3 %鈮?.002
Application:
Used in the manufacture of titanium salts, iridescent agents, artificial pearls, smoke screens, pigments, fabric mordants, etc.
Packaging:Packing: 250kg/drum
Suitable conditions:Store separately from alkalis, oxidants, organics, and combustiblesInorganic Chemicals
website:http://www.flgchem.com/inorganic-chemicals/